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中文名称:碘化铑
英文名称:rhodium(+2) cation triiodide
产品编号:HY-AA-15504
分子式:I3Rh
CAS号:15492-38-3
分子量:483.620
熔点:N/A
密度:N/A
沸点:N/A
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  • 产品特性
  • MSDS
  • 产品规格
  • 询价
  • 碘化铑名称

    中文名碘化铑
    英文名Rhodium triiodide
    中文别名碘化铑(III)
    英文别名更多

    碘化铑物理化学性质

    分子式I3Rh
    分子量483.620
    精确质量483.619446
    LogP2.65710
    外观性状黑色结晶粉末
    储存条件

    常温密闭避光,通风干燥惰性气体下

    稳定性

    常温常压下稳定

    避免的物料:水分/潮湿 氧化物 酸。黑色的固体,单斜系结晶,类似于AlCl3结晶,密度为665g/cm3,在675℃时开始发生分解。

    计算化学

    1、疏水参数计算参考值(XlogP):

    2、氢键供体数量:0

    3、氢键受体数量:3

    4、可旋转化学键数量:0

    5、互变异构体数量:

    6、拓扑分子极性表面积(TPSA):0

    7、重原子数量:4

    8、表面电荷:0

    9、复杂度:0

    10、同位素原子数量:0

    11、确定原子立构中心数量:0

    12、不确定原子立构中心数量:0

    13、确定化学键立构中心数量:0

    14、不确定化学键立构中心数量:0

    15、共价键单元数量:4

    更多

    1.性状:黑色的固体

    2.密度(g/mL,25/4℃):6.65

    3.相对蒸汽密度(g/mL,空气=1):未确定

    4.熔点(oC):未确定

    5.沸点(oC,常压):未确定

    6.沸点(oC,5.2kPa):未确定

    7.折射率:未确定

    8.闪点(oC):未确定

    9.比旋光度(o):未确定

    10.自燃点或引燃温度(oC):未确定

    11.蒸气压(kPa,25oC):未确定

    12.饱和蒸气压(kPa,60oC):未确定

    13.燃烧热(KJ/mol):未确定

    14.临界温度(oC):未确定

    15.临界压力(KPa):未确定

    16.油水(辛醇/水)分配系数的对数值:未确定

    17.爆炸上限(%,V/V):未确定

    18.爆炸下限(%,V/V):未确定

    19.溶解性:未确定

  • MSDS


    Section 1: Product Identification
    Chemical Name:Rhodium (III) iodide (99.9+%-Rh)
    CAS Registry Number:15492-38-3
    Formula:RhI3
    EINECS Number:239-521-5
    Chemical Family:metal halide
    Synonym:Rhodium triiodide

    Section 2: Composition and Information on Ingredients
    IngredientCAS NumberPercentACGIH (TWA)OSHA (PEL)
    Title Compound15492-38-3100%0.01mg/m3 (as Rh0.001mg/m3 (as Rh

    Section 3: Hazards Identification
    Irritating to the respiratory tract. May be harmful if swallowed. Prolonged exposure to iodide salts may
    Emergency Overview:
    produce a mild toxic syndrome known as iodism.
    Primary Routes of Exposure:Contact with skin and eyes. Inhalation of dust.
    Eye Contact:Contact with eyes causes irritation, redness, and pain.
    Skin Contact:Causes irritation to skin. Symptoms include redness, itching, and pain, pimples, boils, hives and blisters.
    Inhalation:Causes irritation to the respiratory tract. Symptoms may include coughing and shortness of breath.
    Ingestion:Large oral doses may cause irritation to the gastrointestinal tract
    Acute Health Affects:Irritating to skin, eyes and respiratory tract.
    Chronic ingestion of iodides may produce iodism. Symptoms include skin rash, running nose, headache and
    Chronic Health Affects:
    irritation of mucous membranes.
    NTP:No
    IARC:No
    OSHA:No

    SECTION 4: First Aid Measures
    Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
    Eye Exposure:
    assistance in keeping their eye lids open. Get immediate medical attention.
    Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
    Skin Exposure:
    irritation persists.
    Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
    Inhalation:
    in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
    Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
    Ingestion:
    vomiting only if directed by medical personnel.

    SECTION 5: Fire Fighting Measures
    Flash Point:not applicable
    Autoignition Temperature:none
    Explosion Limits:none
    Extinguishing Medium:none required
    Special Fire Fighting Procedures:No special fire fighting procedures required.
    Hazardous Combustion andnone
    Decomposion Products:
    Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

    SECTION 6: Accidental Release Measures
    To avoid raising dust, small spills may be mixed with diatomaceous earth, sand, vermiculite or other suitable
    Spill and Leak Procedures:
    inert material and swept up.

    SECTION 7: Handling and Storage
    Handling and Storage:Store solid in a tightly sealed container.

    SECTION 8: Exposure Controls and Personal Protection
    Eye Protection:Always wear approved safety glasses when handling a chemical substance in the laboratory.
    Skin Protection:Wear appropriate chemical resistant gloves and protective clothing.
    Ventilation:If possible, handle the material in an efficient fume hood.
    If in form of fine dust and ventilation is not available a respirator should be worn. The use of respirators
    Respirator:
    requires a Respirator Protection Program to be in compliance with 29 CFR 1910.134.
    Ventilation:If possible, handle the material in an efficient fume hood.
    Additional Protection:No additional protection required.

    SECTION 9: Physical and Chemical Properties
    Color and Form:black pwdr.
    Molecular Weight:483.62
    Melting Point:no data
    Boiling Point:no data
    Vapor Pressure:no data
    Specific Gravity:no data
    Odor:none
    Solubility in Water:slightly soluble

    SECTION 10: Stability and Reactivity
    Stability:hygroscopic
    Hazardous Polymerization:no hazardous polymerization
    Conditions to Avoid:contact with moisture
    Incompatibility:halogens, hydrogen peroxide, chlorates and hypochlorites and active metals
    Decomposition Products:none

    SECTION 11: Toxicological Information
    RTECS Data:No information available in the RTECS files.
    Carcinogenic Effects:no data
    Mutagenic Effects:no data
    Tetratogenic Effects:no data

    SECTION 12: Ecological Information
    Ecological Information:No information available

    SECTION 13: Disposal Considerations
    Disposal:Dispose of according to local, state and federal regulations.

    SECTION 14: Transportation
    Shipping Name (CFR):Non-hazardous
    Hazard Class (CFR):NA
    Additional Hazard Class (CFR):NA
    Packaging Group (CFR):NA
    UN ID Number (CFR):NA
    Shipping Name (IATA):Non-hazardous
    Hazard Class (IATA):NA
    Additional Hazard Class (IATA):NA
    Packaging Group (IATA):NA
    UN ID Number (IATA):NA

    SECTION 15: Regulatory Information
    TSCA:Listed in the TSCA inventory
    SARA (Title 313):Title compound not listed
    Second Ingredient:none


    SECTION 16 - ADDITIONAL INFORMATION
    N/A

    Safety Information

    Safety PhrasesS22-S24/25
    WGK Germany3
    RTECSYU7300000
    Packaging GroupI; II; III
    HS Code2827600000

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